( \(\Rightarrow\) ) Construct triangles \(\triangle ABC\) and \(\triangle DEF\) such that
\begin{align*}
\overline{AB}&\cong\overline{DE},\\
\overline{BC}&\cong\overline{EF},\\
\overline{AC}&\cong\overline{DF}.
\end{align*}
By the Angle Construction Postulate, we can construct a ray \(\overrightarrow{AP}\) such that \(m\angle PAB=m\angle FDE\text{,}\) where \(P\) and \(C\) are in separate half-planes separated by \(\overleftrightarrow{AB}\text{.}\) Then, on ray \(\overrightarrow{AP}\text{,}\) by the Ruler Postulate we can extend this ray and place a point \(F'\) such that \(\overline{AF'}\cong\overline{DF}\text{.}\) By Axiom 1, we can construct the line \(\overline{F'B}\text{.}\) Now, since \(\overline{AF'}\cong\overline{DF}\text{,}\) \(\overline{AB}\cong\overline{DE}\text{,}\) and \(\angle F'AB\cong\angle FDE\text{,}\) we know that \(\triangle ABF'\cong\triangle DEF\) by the SAS Postulate. For the sake of simplicity, we will re-label \(\triangle ABF'\) as \(\triangle DEF\text{.}\) So, we should have the following figure.

Essentially, we place
\(\triangle DEF\) on
\(\triangle ABC\) such that
\(D\) overlaps
\(A\) and
\(E\) overlaps
\(B\text{.}\) By axiom 1, we can construct the segment
\(\overline{CF}\text{.}\)
We observe the new triangles
\(\triangle CDF\) and
\(\triangle CBF\text{.}\) Since
\(\overline{AC}\cong\overline{DF}\) and
\(\overline{BC}\cong\overline{EF}\text{,}\) triangles
\(\triangle CAF\) and
\(\triangle CBF\) are isosceles. By the Isosceles Triangle Theorem,
\(\angle ACF\cong\angle DFC\) and
\(\angle BCF\cong\angle EFC\text{.}\)
Since \(F\) lies in the interior of \(\angle ACB\) and \(C\) lies in the interior of \(\angle DFE\text{,}\) by the Angle Addition Postulate,
\begin{align*}
m\angle ACB&=m\angle ACF+m\angle BCF,\\
m\angle DFE&=m\angle DFC+m\angle EFC.
\end{align*}
Using the fact that \(\angle ACF\cong\angle DFC\) and \(\angle BCF\cong\angle EFC\text{,}\) we see that
\begin{align*}
m\angle ACB&=m\angle DFC+m\angle EFC=m\angle DFE.
\end{align*}
So, we have that
-
\(\overline{AC}\cong\overline{DF}\text{,}\)
-
\(\overline{BC}\cong\overline{EF}\text{,}\)
-
\(\angle ACB\cong\angle DFE\text{.}\)
By the SAS Postulate, \(\triangle ABC\cong\triangle DEF\text{.}\)
( \(\Leftarrow\) ) Suppose \(\triangle ABC\cong\triangle DEF\text{.}\) Then, by definition, their corresponding sides are congruent. So,
\begin{align*}
\overline{AB}\cong\overline{DE},\\
\overline{BC}\cong\overline{EF},\\
\overline{AC}\cong\overline{DF}.
\end{align*}